Electoral-vote.com has this chart, showing the partisan balance in each state’s legislative chamber. The state chambers are arranged in order of Democratic dominance. The state chambers in the middle of the chart are the chambers that are closely balanced. The majority in quite a few chambers could be switched by changes in a small number of districts.
If a significant number of chambers switched from Republican majorities to Democratic majorities, that would make it likely that the National Popular Vote Plan would add additional states in 2021.
States that don’t have legislative elections in November 2020 (except for perhaps a few special elections) are Louisiana, Mississippi, New Jersey, and Virginia.